Routes to develop a [S]/([S]+[Se]) gradient in wide band-gap Cu2ZnGe(S,Se)4 thin-film solar cells

نویسندگان

چکیده

Wide band-gap kesterite-based solar cells are very attractive to be used for tandem devices as well semi-transparent photovoltaic cells. Here, Cu2ZnGe(S,Se)4 (CZGSSe) thin films have been grown by sulfurization of co-evaporated Cu2ZnGeSe4. The influence a NaF precursor layer and Se capping film on CZGSSe absorbers has investigated. It found that the distribution [S]/([S]+[Se]) through absorber is strongly dependent Na content. promotes diffusion S towards bulk layer. Thicker layers>6 nm lead higher content in layer, but decreased accumulation sulphur at surface, detected GIXRD, GD-OES, Raman spectroscopy measurements. A relationship between Jsc, FF Na-content supplied was found; resulted improved cell efficiencies. also possible modify [S]/([S]+[Se])-gradient throughout absence achieving with 2.7% performance Eg = 2.0 eV. This work reveals two ways control depth-profile produce wide band gap layers efficient

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Band Gap Tuning of Cu2ZnGeSxSe4-x Absorbers for Thin-Film Solar Cells

In this work, kesterite-type Cu2ZnGeSxSe4-x absorbers were prepared by a two-step process for use in thin-film solar cells. Their high band gap makes them an interesting candidate as top cells in multijunction solar cells. However, an exact tuning of the band gap is essential. Therefore, for the first time, the [S]/([S] + [Se]) ratio was controlled via addition of a variable amount of GeS durin...

متن کامل

Thin-film Silicon Solar Cells

The simplest semiconductor junction that is used in solar cells for separating photogenerated charge carriers is the p-n junction, an interface between the p-type region and ntype region of one semiconductor. Therefore, the basic semiconductor property of a material, the possibility to vary its conductivity by doping, has to be demonstrated first before the material can be considered as a suita...

متن کامل

Tailoring the Energy Band Gap of Transition Metal Doped TiO2 Thin Film

Water splitting for hydrogen production under sunlight using TiO2 as photo catalyst provides a better route for solar energy and attracts the attention of many researchers. The photo catalytic activity of TiO2 under sunlight irradiation depends on the band gap energy. The transition metal doped TiO2 shows an edge over TiO2 in optical absorbance and photo catalytic activity. Thin film of Cr dope...

متن کامل

Design of Silicon Nano-Bars Anti-Reflection Coating to Enhance Thin Film Solar Cells Efficiency

In this paper a novel anti-reflection (AR) coating based on silicon nano-bars is designed and its impact on the performance of crystalline silicon (c-Si) thin-film solar cells is extensively studied. Silicon nano-bars with optimized size and period are embedded on top of the active layer, under a 100nm Si3N4 layer. As a result of the proposed layer stack, an inhomogeneous intermediate layer wit...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Journal of Alloys and Compounds

سال: 2021

ISSN: ['0925-8388', '1873-4669']

DOI: https://doi.org/10.1016/j.jallcom.2021.159253